Non-contact capacitive coupling electrocardiography (cECG) is considered an effective means for long-term home-based cardiovascular disease monitoring. In this study, a non-contact cECG system was designed to verify the accuracy of heart rate variability (HRV) using cECG signal. Firstly, we established a non-contact cECG acquisition system integrating cECG and ECG modules, achieving synchronization between cECG and ECG signals through a common system clock, which is helpful for our verification. During the validation stage of HRV analysis, we employed signal quality assessment to eliminate poor-quality signals. Subsequently, High-quality cECG signals were processed for R-wave identification to obtain accurate RR intervals and calculate the HRV features, which were then compared with synchronized ECG signals. We analyzed eight different HRV features, including time-domain, frequency-domain, and nonlinear-features. The results demonstrate the feasibility of employing cECG for home-based HRV analysis.